{"id":12258,"date":"2021-09-10T06:05:35","date_gmt":"2021-09-10T12:05:35","guid":{"rendered":"https:\/\/www.ulprospector.com\/knowledge\/?p=12258"},"modified":"2021-12-03T08:54:30","modified_gmt":"2021-12-03T14:54:30","slug":"pc-dispersants-the-understood-misunderstood-additive","status":"publish","type":"post","link":"https:\/\/ulprospector.ul.com\/12258\/pc-dispersants-the-understood-misunderstood-additive\/","title":{"rendered":"Dispersants &#8211; The Understood Misunderstood Additive"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"alignright wp-image-12265 size-full\" src=\"https:\/\/ulprospector.ul.com\/media\/2021\/09\/red-disperants-1.jpg\" alt=\"\" width=\"600\" height=\"400\" srcset=\"https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/red-disperants-1.jpg 600w, https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/red-disperants-1-300x200.jpg 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/>Things transform from a regulatory standpoint and chemistry, especially when you talk about bio-based products or the types of things you need to disperse in a system. Over time, there has been less use of <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/Product\/search?k=Solvent-Borne+Applications&amp;sug=1&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">solvent-based paints<\/a> and an increased use of <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/search?k=carbon+black&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">carbon black<\/a> and new organic pigments that have required up to 200% dispersant solids on pigment. The dispersants are generally high molecular weight and high viscosity.<\/p>\n<p>Making a broad statement, there were only <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/search?k=sodium+dispersant&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">sodium<\/a>, <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/search?k=potassium+dispersant&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">potassium<\/a>, and <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/search?k=ammonium+dispersant&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">ammonium<\/a> dispersants for many years. There were some other ones that serve the purpose for specific applications, such as <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/search?k=pigment+slurry&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">pigment slurries<\/a> or even <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/search?k=soya+lecithin&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">soya lecithin<\/a> for colorants. But the change in pigments for many applications necessitated a like change in dispersants. It wasn&#8217;t enough to change the molecular weight of dispersants. Equipment was created to disperse materials faster in the laboratory, which led to scale up to production.<\/p>\n<p>A dispersant is an additive that increases the permanency of a suspension of pigments in a liquid medium. The pigment-dispersing step is the most challenging and time\/energy consuming part of the paint manufacturing process. This is generally because of the difference in surface energy between the solids (pigments and extenders) and liquids (polymers and solvents. The grinding of the agglomerates are dissociated into a dispersion of particles. In the process, dispersants (<a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/Product\/search?k=Surfactants&amp;sug=1&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">surfactants<\/a>) are used that mainly prevent reassociation of the pigment and extender particles. The dispersants are adsorbed onto the particles and hinder close approach of particles by charge repulsion effects (ionic dispersants) or by steric effects (nonionic dispersants).<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"aligncenter wp-image-12263\" src=\"https:\/\/ulprospector.ul.com\/media\/2021\/09\/wetting-grinding-stabilization.png\" alt=\"diagram of wetting, grinding and stabilization\" width=\"600\" height=\"129\" srcset=\"https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/wetting-grinding-stabilization.png 484w, https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/wetting-grinding-stabilization-300x64.png 300w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><\/p>\n<p>Dispersing and wetting agents are utilized to stabilize pigment dispersions. They often use steric hindrance to avoid flocculation of the pigment particles. Since a dispersant is used to help the suspension of fine particles of a solid in a liquid phase, it must be able to totally wet the solid particle and eliminate any and all air between the pigment and liquid medium. Dispersants act by being absorbed on the surface of the pigment particles with the other end of the molecule exposed and usually charged. Like charges repel, the independently coated pigment particles repel each other and stay uniformly dispersed.<\/p>\n<p>Because the individual pigments are all so chemically different \u2013 some are attracted to water, and some are not \u2013 the dispersants have to be chemically different. Pigment dispersants are necessary to improve the wetting of the pigment and enhance its suspension. The choice of dispersant depends on the nature of the pigments and if the coating is a waterborne or solvent-borne system. Dispersants are offered for organic and inorganic pigment systems and for both solvent- and waterborne systems. Pigment dispersion is one of the most important, critical and complex steps in paint manufacture.<\/p>\n<figure id=\"attachment_12260\" class=\"thumbnail wp-caption alignright\" style=\"width: 450px\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-12260 size-full\" src=\"https:\/\/ulprospector.ul.com\/media\/2021\/09\/dispersion.jpg\" alt=\"depiction of how dispersion works\" width=\"450\" height=\"188\" srcset=\"https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/dispersion.jpg 450w, https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/dispersion-300x125.jpg 300w\" sizes=\"(max-width: 450px) 100vw, 450px\" \/><figcaption class=\"caption wp-caption-text\">Dispersion<\/figcaption><\/figure>\n<p>In the wetting stage, the liquid in the mill displaces air from the pigment surfaces. Shear force, applied by a mill, is necessary to break down pigment agglomerates. As pigment particles become adequately dispersed, dispersants that are now on the surface of the pigment particles\u00a0prevent reagglomeration of the pigment.<\/p>\n<p>Because of their hydrophobic nature, organic pigments are challenging to disperse in aqueous media. Surface-active compounds that are amphoteric in nature are usually effective for both organic and inorganic pigments that are particularly hydrophobic.<\/p>\n<figure id=\"attachment_12261\" class=\"thumbnail wp-caption alignright\" style=\"width: 479px\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-12261 size-full\" src=\"https:\/\/ulprospector.ul.com\/media\/2021\/09\/electrical-double-layer-on-pigment-surfaces.png\" alt=\"diagram of the electrical double layer on pigment surfaces\" width=\"479\" height=\"196\" srcset=\"https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/electrical-double-layer-on-pigment-surfaces.png 479w, https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/electrical-double-layer-on-pigment-surfaces-300x123.png 300w\" sizes=\"(max-width: 479px) 100vw, 479px\" \/><figcaption class=\"caption wp-caption-text\">Electrical double layer on pigment surfaces<\/figcaption><\/figure>\n<p>In aqueous systems, dispersants must disperse the pigment and form an affiliation between the pigment and the dispersing medium that is water. This is especially true with carbonaceous materials such as carbon nanotubes. There are ionic water-loving (hydrophilic) and oil-loving (lipophilic) types available on the market. The hydrophobic part of the molecule is attracted to the pigment particle and surrounds the particle with an ionic layer. Pigment separation by mutual repulsion takes place. These cannot be relied on for in-can stability and need to be used then with nonionic surfactants. Ionic, anionic and amphoteric surfactants are also essential for good dispersion, and contribute to the latex paint system by helping to optimize hiding power, flow, and leveling.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-12259 alignright\" src=\"https:\/\/ulprospector.ul.com\/media\/2021\/09\/binder-compatible-chain.png\" alt=\"diagram of the binder compatible chain\" width=\"455\" height=\"186\" srcset=\"https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/binder-compatible-chain.png 455w, https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2021\/09\/binder-compatible-chain-300x123.png 300w\" sizes=\"(max-width: 455px) 100vw, 455px\" \/><\/p>\n<p>Pigments are usually easier to disperse in solvent-borne resin systems; however, higher solids systems will sometimes show pigment flocculation problems. This can be the result of the lower-molecular-weight polymers or oligomers having less of a buffering effect on the pigments and thereby permitting closer pigment-to-pigment contact. These are zero-VOC and alkyl phenol-free to allow reformulation of existing platforms to comply with new requirements. Amphoteric dispersants have been developed that are effective for preventing flocculation of carbon black and other organic and inorganic pigments in higher-solids systems. These dispersants have also been able to keep viscosity from acetylenic diols are also sometimes added. Another widely used class of dispersants is based on soya lecithin. These have been used for many years as pigment wetting agents, grinding aids and dispersion stabilizers in oleoresinous formulas. This class of agent is also available in water-soluble or water-dispersible forms. These are used in much the same applications in latex formulations. The water-compatible versions are also very useful in formulating universal colorants and as agents in both water and solvent formulas to improve universal colorant compatibility and color development. Typically, pigments are used to modify the optical properties of a cured film by introducing decorative color, enhancing opacity or controlling gloss. In addition to promoting visual effects, these materials are also commonly used as <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/Product\/search?k=Thickeners+%2F+Rheology+Modifiers&amp;sug=1&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">rheology modifiers<\/a>, <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/Product\/search?k=Extenders+%2F+Fillers+%2F+Reinforcements&amp;sug=1&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">extenders<\/a> and <a href=\"https:\/\/www.ulprospector.com\/en\/na\/Coatings\/Product\/search?k=Corrosion+Protection+Additives&amp;sug=1&amp;st=31&amp;utm_source=KnowledgeCenter&amp;utm_medium=article&amp;utm_campaign=2021pc&amp;utm_term=dispersents\" target=\"_blank\" rel=\"noopener\">corrosion inhibitors<\/a>. However, in all cases, the key to efficiently promoting the desired functionality rests with the ability to control both the distribution and particle size of the added pigment(s) within a coating\u00a0formulation.<\/p>\n<p>The first factor is, of course, the additive\u2019s influence upon wetting and dispersing properties; the second factor is the summation of the additive\u2019s influence upon all the properties within the formulated coating system.<\/p>\n<p><strong>Other resources:<\/strong><\/p>\n<p><a href=\"http:\/\/www.inkline.gr\/inkjet\/newtech\/tech\/dispersion\/\" target=\"_blank\" rel=\"noopener\">http:\/\/www.inkline.gr\/inkjet\/newtech\/tech\/dispersion\/<\/a><\/p>\n<p><a href=\"https:\/\/www.pcimag.com\/articles\/108710-novel-specialty-dispersant-for-carbon-black-in-industrial-waterborne-systems\" target=\"_blank\" rel=\"noopener\">Novel Specialty Dispersant for Carbon Black in Industrial Waterborne Systems | 2021-05-05 | PCI Magazine<\/a><\/p>\n<p><a href=\"https:\/\/www.lubrizol.com\/Coatings\/Blog\/2018\/12\/Pigment-Dispersants-Yield-Colorful-High-Performance-Results\" target=\"_blank\" rel=\"noopener\">Pigment Dispersants Yield Colorful, High-Performance Results &#8211; Lubrizol<\/a><\/p>\n<p><a href=\"https:\/\/insights.basf.com\/home\/article\/read\/strengthen-and-streamline-your-automotive-coating-formulations\" target=\"_blank\" rel=\"noopener\">High-Performance Dispersants for Automotive Paints | Where business meets science (basf.com)<\/a><\/p>\n<p><a href=\"https:\/\/www.paint.org\/coatingstech-magazine\/articles\/improved-durability-through-reactive-dispersant-technology\/\" target=\"_blank\" rel=\"noopener\">Improved Durability through Reactive Dispersant Technology &#8211; American Coatings Association (paint.org)<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Things transform from a regulatory standpoint and chemistry, especially when you talk about bio-based products or the types of things you need to disperse in a system. Over time, there has been less use of solvent-based paints and an increased &hellip; <a href=\"https:\/\/ulprospector.ul.com\/12258\/pc-dispersants-the-understood-misunderstood-additive\/\">Continued<\/a><\/p>\n","protected":false},"author":26,"featured_media":12262,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"_monsterinsights_skip_tracking":false,"_monsterinsights_sitenote_active":false,"_monsterinsights_sitenote_note":"","_monsterinsights_sitenote_category":0,"episode_type":"","audio_file":"","podmotor_file_id":"","podmotor_episode_id":"","cover_image":"","cover_image_id":"","duration":"","filesize":"","filesize_raw":"","date_recorded":"","explicit":"","block":"","itunes_episode_number":"","itunes_title":"","itunes_season_number":"","itunes_episode_type":"","footnotes":""},"categories":[16],"tags":[],"ppma_author":[1242],"class_list":{"0":"post-12258","1":"post","2":"type-post","3":"status-publish","4":"format-standard","5":"has-post-thumbnail","7":"category-paint-coatings","8":"entry"},"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v27.3 - https:\/\/yoast.com\/product\/yoast-seo-wordpress\/ -->\n<title>Dispersants - The Understood Misunderstood Additive<\/title>\n<meta name=\"description\" content=\"Dispersants are additives that increase the permanency of a suspension of pigments in a liquid medium. 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In his career, he has formulated architectural, industrial, military and specialty coatings. He has also worked with and formulated adhesives, inks, and construction products and in general is a material science generalist. He has a keen interest in Sustainable and Bio-based paints, inks, adhesives and elastomers. He was a Developmental Scientist in the Advanced Materials group at Luna Labs 2004-2008, formulating military coatings and adhesives. Previously, he was at Dow Chemical (1999-2004) as the applications and development manager in Core R&amp;D in the Coatings &amp; Functional Polymers Group. He also managed the TS&amp;D group for coatings while at Dow Chemical (1995-99) and held positions at Rhodia (Laboratory Manager, Latex &amp; Specialty Polymers (1989-95)) and was the Development Chemist, exterior latex paints at Benjamin Moore &amp; Co. (1979-89). Mr. Hirsch has served in a consultancy capacity as a Director with the ChemQuest group, (chemquest.com) June 2021-March 2025 at OmniTech (omnitechintl.com) (2015-2022) for soy-based adhesives and coatings, Daikin America (daikin-america.com) (2011-2015) fluoropolymers and materials, and also with organizations that provide formal mentoring (TORCH 2018-present), coaching and leadership training, as well as the facilitation of problem-solving teams. He has several granted patents, many patent applications and internal disclosures for trade secrets. Connect with Marc on LinkedIn...\",\"sameAs\":[\"https:\\\/\\\/ulprospector.ul.com\",\"https:\\\/\\\/www.linkedin.com\\\/in\\\/marchirsch\\\/\"],\"url\":\"https:\\\/\\\/ulprospector.ul.com\\\/author\\\/marc-hirsch\\\/\"}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Dispersants - The Understood Misunderstood Additive","description":"Dispersants are additives that increase the permanency of a suspension of pigments in a liquid medium. Learn more here:","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/ulprospector.ul.com\/12258\/pc-dispersants-the-understood-misunderstood-additive\/","og_locale":"en_US","og_type":"article","og_title":"Dispersants - The Understood Misunderstood Additive","og_description":"Dispersants are additives that increase the permanency of a suspension of pigments in a liquid medium. 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In his career, he has formulated architectural, industrial, military and specialty coatings. He has also worked with and formulated adhesives, inks, and construction products and in general is a material science generalist. He has a keen interest in Sustainable and Bio-based paints, inks, adhesives and elastomers. He was a Developmental Scientist in the Advanced Materials group at Luna Labs 2004-2008, formulating military coatings and adhesives. Previously, he was at Dow Chemical (1999-2004) as the applications and development manager in Core R&amp;D in the Coatings &amp; Functional Polymers Group. He also managed the TS&amp;D group for coatings while at Dow Chemical (1995-99) and held positions at Rhodia (Laboratory Manager, Latex &amp; Specialty Polymers (1989-95)) and was the Development Chemist, exterior latex paints at Benjamin Moore &amp; Co. (1979-89). Mr. Hirsch has served in a consultancy capacity as a Director with the ChemQuest group, (chemquest.com) June 2021-March 2025 at OmniTech (omnitechintl.com) (2015-2022) for soy-based adhesives and coatings, Daikin America (daikin-america.com) (2011-2015) fluoropolymers and materials, and also with organizations that provide formal mentoring (TORCH 2018-present), coaching and leadership training, as well as the facilitation of problem-solving teams. He has several granted patents, many patent applications and internal disclosures for trade secrets. Connect with Marc on LinkedIn...","sameAs":["https:\/\/ulprospector.ul.com","https:\/\/www.linkedin.com\/in\/marchirsch\/"],"url":"https:\/\/ulprospector.ul.com\/author\/marc-hirsch\/"}]}},"authors":[{"term_id":1242,"user_id":26,"is_guest":0,"slug":"marc-hirsch","display_name":"Marc Hirsch","avatar_url":"https:\/\/ulprospector.ul.com\/wp-content\/uploads\/2022\/10\/IMG_1016-scaled.jpg","0":null,"1":"","2":"","3":"","4":"","5":"","6":"","7":"","8":""}],"_links":{"self":[{"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/posts\/12258","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/users\/26"}],"replies":[{"embeddable":true,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/comments?post=12258"}],"version-history":[{"count":0,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/posts\/12258\/revisions"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/media\/12262"}],"wp:attachment":[{"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/media?parent=12258"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/categories?post=12258"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/tags?post=12258"},{"taxonomy":"author","embeddable":true,"href":"https:\/\/ulprospector.ul.com\/wp-json\/wp\/v2\/ppma_author?post=12258"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}